Like for any scraping your first need to connect your Sales Navigator account to Vayne, using your session cookie (it is not the case already).
Then, you need to searches for accounts in Sales Navigator. Additional company filters are available in the accounts tab instead of the leads tab.
In the example below, we are filtering large companies (10,001+ employees), headquartered in New York City:

Once you have indicated the filters you needed, simply get the Sales Navigator URL from your browser, like in the example below :
<aside> 🔗
https://www.linkedin.com/sales/search/company?query=(filters%3AList((type%3ACOMPANY_HEADCOUNT%2Cvalues%3AList((id%3AI%2Ctext%3A10%25C2%25A0001%2520et%2520%252B%2CselectionType%3AINCLUDED)))%2C(type%3AREGION%2Cvalues%3AList((id%3A105080838%2Ctext%3ANew%2520York%252C%2520%25C3%2589tats-Unis%2CselectionType%3AINCLUDED)))))&viewAllFilters=true
</aside>
You can then create a new order directly in Vayne in the Accounts tab :

Copy your URL in the window and then name your order (orders’ name must unique) :

Once the data are scraped, you can download them as a .csv file. The list of fields that are collected can be find below.